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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Thermal rearrangement of aromatic hydrocarbons ： ウィキペディア英語版 Thermal rearrangement of aromatic hydrocarbons Thermal rearrangements of aromatic hydrocarbons are considered to be unimolecular reactions that directly involve the atoms of an aromatic ring structure and require no other reagent than heat. These reactions can be categorized in two major types: one that involves a complete and permanent skeletal reorganization (isomerization), and one in which the atoms are scrambled but no net change in the aromatic ring occurs (automerization).〔Scott, L. T. (Thermal Rearrangements of Aromatic Compounds ). ''Acc. Chem. Res.'' 1982, 15 (2), 52–58. DOI: 10.1021/ar00074a004〕 The general reaction schemes of the two types are illustrated in Figure 1. This class of reactions was uncovered through studies on the automerization of naphthalene as well as the isomerization of unsubstituted azulene, to naphthalene. Research on thermal rearrangements of aromatic hydrocarbons has since been expanded to isomerizations and automerizations of benzene and polycyclic aromatic hydrocarbons. ==Mechanisms== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Thermal rearrangement of aromatic hydrocarbons」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.